Iodidobis(morpholine-4-carbodithioato-κ2 S,S′)(1,10-phenanthroline-κ2 N,N′)bismuth(III)
نویسندگان
چکیده
The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi-thio-ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa-hedral geometry.
منابع مشابه
Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3 O,O′:O′;κ3 O:O:O′;κ2 O:O′;κ2 O:O′-bis[(3,4-dimethoxyphenylacetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N)thulium(III)]
In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging...
متن کاملBis(2,6-dihydroxybenzoato-κ2 O 1,O 1′)(nitrato-κ2 O,O′)bis(1,10-phenanthroline-κ2 N,N′)neodymium(III)
In the mononuclear title complex, [Nd(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Nd(III) atom is in a distorted bicapped square-anti-prismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihy-droxy-benzoate (DHB) ligands and two O atoms from a nitrate anion. π-π stacking inter-actions between the phen and DHB ligands of a...
متن کاملBis(μ-N-acetyl-N-phenylglycinato-κ2 O:O′)bis[dinitrato-κ4 O,O′-bis(1,10-phenanthroline-κ2 N,N′)lanthanum(III)]
In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl-glycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-anti-prismatic coordination, are bridged by two N-ace...
متن کامل1,10-Phenanthrolin-1-ium nitrate–aquabis(4-hydroxybenzoato-κ2 O,O′)(nitrato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)erbium(III)–1,10-phenanthroline–water (1/1/0.5/2)
In the title compound, C(12)H(9)N(2) (+)·NO(3) (-)·[Er(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))(H(2)O)]·0.5C(12)H(8)N(2)·2H(2)O, the water-mol-ecule-coordinated Er(III) ion is chelated by one 1,10-phenanthroline (phen) ligand, two 4-hy-droxy-benzoate anions and one nitrate anion in a monocapped square-anti-prismatic coordination geometry. The uncoordinating phen mol-ecule is approximately paralle...
متن کامل(6-Oxido-2-oxo-1,2-dihydropyrimidine-5-carboxylato-κ2 O 5,O 6)(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ2 O 4,O 5)bis(1,10-phenanthroline-κ2 N,N′)erbium(III) dihydrate
The erbium(III) atom in the title compound, [Er(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, is located on a twofold rotation axis and chelated by two 1,10-phenanthroline heterocycles as well as by a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate monoanion and a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate dianion in a square-anti-prismatic coordination geometry.
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014